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Lecture Notes on Surface
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Lecture Notes on Surface
Contents
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Introduction and Ultra High Vacuum (UHV)
Format of this lecture series
Introduction
Some Surface Science books and www-links
Ultra High Vacuum (UHV)
Vacuum requirements
Pumping and bakeout[
7
]
Pressure measurement[
7
]
Materials and construction[
7
]
Chemical analysis of the rest gas[
7
]
Further reading
Electron spectroscopy
Introduction
Why electrons: The mean free path
Electron sources and analysers
Electrons in solids: elastic and inelastic scattering
The dielectric function
Phonons
Excitons
Interband transitions
Bulk and surface plasmons
Core levels
Concluding remarks
Further reading
Desorption
Adsorption-desorption equilibrium
Single-crystal adsorption calorimetry
Chemical reactions and catalysis
Further reading
Surface Structure
Surface Thermodynamics and general crystal shape
Surface geometry: truncated bulk, relaxation, reconstruction, defects and super-structures
General phenomena
Lattice and reciprocal lattice
Low energy electron diffraction (LEED), LEED patterns and quantitative structure determination
Instrumentation
Diffraction pattern and their analysis
Diffraction from a two-dimensional lattice
Diffraction from a surface
Interpretation of LEED patterns
Quantitative structure determination
Some examples from LEED structure determination
Metal surfaces
Semiconductor surfaces
Insulator surfaces
Other scattering techniques
Extended X-ray Absorption Fine Structure (EXAFS and Surface EXAFS (SEXAFS)
EXAFS
SEXAFS
Photoelectron diffraction (PhD, PED)
Introduction
Simple Theory
Structure determination: experimental results
Angle-scan photoelectron diffraction: forward scattering
Scanned-energy mode photoelectron diffraction: backscattering
Suggested reading
Scanning Tunnelling Microscopy
Basic principle and experimental setup
Theory of operation
Clean metal surfaces
Adsorbates on metal surfaces
Adsorbate induced reconstruction of metal surfaces
Semiconductor surfaces
Insulator surfaces
Other applications and further instrumental development
Further reading
The electronic structure of surfaces
Work function
Electronic surface states: basic ideas
Measuring the electronic structure of surfaces with angle-resolved photoemission
Introduction
The photoemission process
Theory
Photoexcitation from molecules
Photo-excitation in a periodic potential
Instrumentation
The three step model
Band mapping: 2d bands and 3d bands
Some surface states investigated by ARPES
Clean metal surfaces
Adsorbate covered metal surfaces
Semiconductor surfaces
Semimetal surfaces
Scanning Tunnelling Spectroscopy
Further Reading
Optical properties of surfaces
Reflection of Light at a Surface
Polaritons
Reflection Anisotropy Spectroscopy (RAS)
Second Harmonic Generation
Vibrational properties of surfaces
Introduction
Electron scattering: EELS
Optical spectroscopy: IRAS
He Atom scattering
Vibrational spectroscopy with the STM
Further reading
References
Index
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